Your feet are different shapes everyones are. All boots are different and that's why we have boot fitters. It sounds like the main issue is that the boots you have cater a fitting to your right foot instead of your left. Get a pair of boots that fit your left foot better with a little tweaking, but that also fit the right with just a little tweaking. It sounds like I am being an ass, but really, if both your feet were shaped like your left, and your boots were that uncomfortable the equation would be as simple as saying you have the wrong boots. Because you got lucky enough to get your right foot fit into the wrong boots with just a few punches doesn't mean you don't have the wrong boots.
Second: does your left boot hurt wearing on the couch, or only when you are making turns? If it only hurts turning, the relation to golfing isn't the difference in the static shape of you foot. it's in the geometry of your motion. you probably have very assymetrical turn mechanics. Golf, and also hockey are very assymetrical sports and your legs hips and ankles are probably not making motions between left and right turns. Sorry for the novel, hope it helps.
Growing up I was a very technical skier at a tiny ski hill, now when I go back, I just take the whole thing in ... with flexion, then extension. And yeah I am over it.
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