You shouldn't need any food on a run that length. Electrolytes maybe if it's hot enough, but definitely no food. Here's Endurance Nutrition 101:
Depending on bodyweight, pace, and individual neuromuscular efficiency, most people will burn 600-800 calories per hour during endurance exercise, but can only digest about 200 cal/hr at most. What that means is that endurance exercise is a calorie deficit activity. Thankfully, your body fat is a massive energy reservoir. For the sake of easy math, let's say you are a small, lean individual weighing 150 lbs and 10% body fat (15 pounds of body fat). About one-third that body fat (BF) is not bioavailable because if BF gets too low you die. So, you have 10 lbs of available BF to draw upon for energy, or roughly 35,000 total calories at 3,500 cals/lb. That is a shitload of energy, and we're talking a very lean 10% BF individual. Even someone mildly overweight has tens of thousands more calories on them.
The catch is that your BF can only be released and metabolized so quickly, 400-500 cals/hr depending on the individual. Obviously, 400-500 is less than 600-800 so you have two options: slow down to <70% of your max HR (slow enough that caloric demand drops low enough to be met 100% by BF), or make up the difference. Short term you can make up the difference with glycogen (intramuscular starch). Glycogen storage is relative to muscle mass, so depending on body size and body composition you can carry 1,000-2,000 cals as glycogen. This is why there is no need for food on runs under two hours. You can also improve your fat burning capability through training and diet, but that's a different discussion.
If you will be out longer than 2-3 hours and want or need to maintain a pace faster than 70% of max HR you need to ingest some calories (and it’s preferable not to deplete your glycogen, your muscles function best when not glycogen depleted. You also stay hydrated better, every gram of glycogen stores 4 grams of water). The vast majority of those calories should be from starch/polysaccharides since they are calorie-dense and digested very easily. Maltodextrin is the starch you will find in virtually all Gu-type products. Whole food starches are fine too, just keep the fiber content to a minimum. My current personal favorite is peeled cubed potatoes cooked in heavily salted water. I’m not a fan of anything in drink form. I find them pretty unpalatable when warm and you want to avoid simple sugars anyway which is what most are. SuperStarch is an interesting new product that I have yet to try, but I know bagtagely has used it with good results.
After about 3 hours, your body needs amino acids to continue producing energy. If you do not ingest any amino acids your body will get them from the only other place it can—your muscles. This is bad, very bad. Specialty endurance foods with aminos in them work great, but so does eating a few small bites of jerky or other complete protein every hour or so. Small amounts of fat are helpful at this point too as they help to buffer stomach acid. Those little individual packets of nut butters are great for this.
Don’t over drink. Dehydration kills you slowly, hyponatremia kills you fast. Electrolyte supplements are crucial during extended efforts in hot weather (generally >80* F). I’m not a fan of stuff like Nuun that you put in your water. I prefer caplet-style ones like S-Caps or Saltstick Caps. You can even make these on the cheap by buying empty gelcaps in bulk and filling them with table salt.
Reason? While you don’t want caffeine to be a crutch it’s a powerful tool in the toolkit. Besides the stimulant effect, caffeine boosts your mobilization of fatty acids from BF and can help ease headaches. I always carry caffeine with me on long runs/rides. Sometimes I use it, sometimes I don’t, but it has saved my ass a couple times.
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